What is Molecular Mass

What is Molecular Mass 

Molecular mass/Formula mass
Molecular mass expresses as to how many times a molecule of a substance is heavier than th of the mass of an atom of carbon (carbon-12).
Thus, Molecular mass = \(\frac { Mass\quad of\quad a\quad molecule }{ \frac { 1 }{ 12 } th\quad mass\quad of\quad a\quad carbon\quad atom\quad (carbon-12) } \)
Molecular mass = 2 × vapour density
Example: A molecule of water is 18 times heavier than th of the mass of carbon atom. Therefore, the molecular mass of water is 18 u.

Calculation of molecular mass from atomic masses
The molecules are made up of two or more atoms of different elements. Therefore, the molecular mass may be calculated as the sum of the atomic masses of all the atoms in a molecule of that substance.
Example: Ammonia has the formula, NH3. it consists of one atom of N and three atoms of H. The atomic mass of N and H are 14.0 and 1 respectively. Therefore, the molecular mass of NH3 is
Molecular mass of NH3 = Atomic mass of N + 3 × Atomic mass of H
= 14 + 3 × 1 = 17 u

Example: Sulphuric acid has the formula H2SO4. It consists of two H, one S and four O atoms. The atomic masses of H, S and O are 1,32 and 16 respectively. Therefore, the molecular mass of H2SO4 is
Molecular mass of H2SO4 = (2 × Atomic mass of H) + (1 × Atomic mass of S) + (4 × Atomic mass of O)
= (2 × 1) + (1 × 32) + (4 × 16) = 98 u

Gram molecular mass
The molecular mass of a substance expressed in gram is called its gram molecular mass.
Example: Molecular mass of oxygen, O2 = 32 u
So, gram molecular mass of oxygen, O2 = 32 grams.

People also ask

What is the atomic mass of an element?

What is the atomic mass of an element?

Atomic mass

  • Atoms are extremely small; the heaviest atoms have masses of about 10–22 g. Even an ultramicrobalance cannot measure the mass of a single atom. However, relative masses of atoms of different elements can be determined. At first, the mass of the lightest atom, hydrogen.
  • The SI unit for mass is kilogram (kg).
  • The mass of some typical objects which we come across in our daily lives are as shown in Table.
    atomic mass
  • Atoms and subatomic particles like the proton and neutron have very small masses. If the unit kilogram is used, the mass has to be written in the standard form. A heavy atom like americium-241 has a mass of 4.00 × 10–25 kg. The mass of a proton is 1.67 × 10–27 kg. This means that the kilogram is too large a unit for the mass of atoms.

What is meant by AMU?

    • In 1961, International Union of chemists selected the most stable isotope of carbon (C-12 isotope) as standard for comparison the atomic masses of various elements. Atomic mass of an element tells us the number of times an atom of the element is heavier than of the mass of an atom of carbon-12.
    • A unit suitable for the mass of atoms and the mass of subatomic particles is the atomic mass unit (u).
    • In the definition of the atomic mass unit, the carbon-12 isotope has been chosen to be the reference element. One carbon-12 atom is defined to have a mass of exactly 12 u.
    • Atomic mass of an element may be defined as the average relative mass of an atom of the element as compared with mass of an atom of carbon (C-12 isotope) taken as 12 amu.
    • Therefore, 1 u is defined as \(\frac { 1 }{ 12 } \) of the mass of a carbon-12 atom.
    • It has been found experimentally that the mass of one carbon-12 atom is 1.99265 × 10–26 kg
      Therefore, 1 u = \(\frac { 1 }{ 12 } \) × 1.99265 × 10–26 kg
      1 u = 1.66 × 10–27 kg
    • Table gives the mass of some subatomic particles and atoms.
      atomic mass unit 2
  • The values given in Table (b) are the masses of the neutral atoms (which includes the mass of the electrons and not the mass of the nucleus only). For example, the value 4.002 603 u for the mass of a helium-4 atom includes the mass of its 2 electrons.
  • When atomic masses are added or subtracted, the answer should be written with the same number of decimal places.

What is the formula for calculating atomic mass?

\(Atomic\quad mass=\frac { Mass\quad of\quad 1\quad atom\quad of\quad the\quad element }{ \frac { 1 }{ 12 } of\quad the\quad Mass\quad of\quad an\quad atom\quad of\quad carbon\quad -\quad 12\quad  } \)
Example:    The atomic mass of magnesium is 24 u which indicates that one atom of magnesium is 24 times heavier than \(\frac { 1 }{ 12 } \) of a carbon 12 atom.

People also ask

Atomic Mass of Some ElementsGram atomic mass

Gram atomic mass of an element is defined as that much quantity of the element whose mass expressed in grams is numerically equal to its atomic mass. To find gram atomic mass we keep the numerical value the some as the atomic mass, but simply change the units from u to g. for example, atomic mass of aluminium is 27 u. Its gram atomic mass is 27 g.

Gram atomic mass of Isotopes :
Gram atomic mass of Isotopes = \(\frac { { M }_{ 1 }{ X }_{ 1 }+{ M }_{ 2 }{ X }_{ 2 } }{ { X }_{ 1 }+{ X }_{ 2 } } \)
M1 & M2 are relative masses of isotopes and X1 & X2 are relative % content
Example: Chlorine contains two types of atoms having relative masses 35 and 37 and their relative abundance is 3 : 1. In such cases the atomic mass of the element is the average of relative masses of different isotopes of the element.
Atomic mass of chlorine = \(\frac { 35\times 3+37\times 1 }{ 4 } \) = 35.5

S.noElementSymbolAtomic mass
1HydrogenH1 u
2CarbonC12 u
3NitrogenN14 u
4OxygenO16 u
5SodiumNa23 u
6MagnesiumMg24 u
7AluminiumAl27 u
8PhosphorusP31 u
9SulphurS32 u
10ChlorineCl35.5 u
11PotassiumK39 u
12CalciumCa40 u
13IronFe56 u
14CopperCu63.5 u

Atomic Mass Problems with Solutions

  1. What is the difference in mass of a proton and a neutron? Use the data in Table and state your answer in kilograms.
    Solution:
    Atomic Mass Problems
  2. Express the mass of an electron as a fraction of the mass of a proton.
    Solution:
    Atomic Mass Problems 1