{"id":14823,"date":"2020-12-01T10:27:41","date_gmt":"2020-12-01T04:57:41","guid":{"rendered":"https:\/\/cbselibrary.com\/?p=14823"},"modified":"2020-12-01T15:29:48","modified_gmt":"2020-12-01T09:59:48","slug":"enthalpy-heat-combustion","status":"publish","type":"post","link":"https:\/\/cbselibrary.com\/enthalpy-heat-combustion\/","title":{"rendered":"What is the heat of combustion?"},"content":{"rendered":"
<\/p>\n
Heat of Combustion:<\/strong><\/p>\n <\/p>\n People also ask<\/strong><\/p>\n Determining the heat of combustion:<\/strong><\/p>\n In the laboratory, the heat of combustion of a fuel can be determined as follows.<\/p>\n One example of liquid fuel is alcohol. Different members of the alcohol family have different heat of combustion. The table below shows the heat of combustion of some alcohols.<\/p>\n Table shows that the heat of combustion of alcohol increases as the<\/p>\n During the combustion of alcohol:<\/p>\n The difference in the heat of combustion of successive members is almost the same, that is, about 650 kJ.<\/p>\n (a) Successive members of the homologous series of alcohols differ from each other by a -CH2<\/sub> group. When the heat of combustion is plotted against the number of carbon atoms per alcohol molecule, the graph in Figure is obtained. Aim:<\/strong> To investigate whether an alcohol with a higher number of carbon atoms per molecule has a higher heat of combustion. Results: Interpreting data:<\/strong> Conclusion:<\/strong> 1.\u00a0<\/strong>Complete combustion of 1 mole of butan-l-ol, C4<\/sub>H9<\/sub>OH produces 2678 kJ of heat. Calculate the mass of butan-l-ol needed to burn completely in excess oxygen in order to raise the temperature of 500 cm3<\/sup> of water by 35\u00b0C. 2.\u00a0<\/strong>An experiment is carried out to determine the heat of combustion of ethanol, C2<\/sub>H5<\/sub>OH. The results of the experiment are shown below. What is the heat of combustion? What is the definition of enthalpy of combustion? Heat of Combustion: A fuel is a chemical substance that burns in oxygen to produce heat energy. Combustion is a chemical reaction between a fuel and oxygen to release heat. Combustion is always an exothermic reaction. The heat of combustion … Read more<\/a><\/p>\n","protected":false},"author":3,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"spay_email":""},"categories":[84],"tags":[5891,5819,5895,5894,5890,5893,5898,5897,5823,5884,5883,5892,5888,5889,5885,5886,5821,5822,5820,5813,5887,5818,5882,5896],"yoast_head":"\n\n
\n(a) Combustion of elements
\n<\/strong>C(s) + O2<\/sub>(g) \u2192\u00a0CO2<\/sub>(g) \u00a0 \u00a0\u0394H = -394 kJ
\nWhen 1 mole of carbon burns completely in oxygen to form carbon dioxide, 394 kJ of heat is released. The heat of combustion of carbon is -394 kJ mol-1<\/sup>. The energy level diagram for the combustion of carbon is as shown below.
\n
\n(b) Combustion of compounds
\n<\/strong>CH4<\/sub>(g) + O2<\/sub>(g) \u2192\u00a0CO2<\/sub>(g) + 2H2<\/sub>O(l)
\n<\/strong>When 1 mole of methane burns completely in oxygen to form carbon dioxide and water, 890 kJ of heat is released. The heat of combustion of methane is -890 kJ mol-1<\/sup>. The energy level diagram for the combustion of methane is as shown in Figure.
\n<\/li>\n
\n(a) In excess oxygen, 1 mole of carbon burns completely to form carbon dioxide and produce 394 kJ of heat.
\nC(s) + O2<\/sub>(g) \u2192\u00a0CO2<\/sub>(g) \u00a0 \u00a0\u0394H = -394 kJ
\n(b) In limited supply of oxygen, 1 mole of carbon burns to form carbon monoxide and produce 108 kJ of heat.
\nC(s) + \u00bd\u00a0O2<\/sub>(g) \u2192\u00a0CO2<\/sub>(g) \u00a0 \u00a0\u0394H = -108 kJ
\nNote:\u00a0<\/strong>The heat of combustion of carbon is -394 kJ mol-1<\/sup>\u00a0and not -108 kJ mol-1<\/sup>.<\/li>\n\n
\n<\/a><\/li>\nDetermination of heat combustion by bomb calorimeter<\/strong><\/h2>\n
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\n<\/li>\n<\/ol>\n\n
\nHeat given out during combustion of the fuel = heat absorbed by the water<\/li>\nHeat of combustion of various alcohols<\/strong><\/h2>\n
\n\n
\n Alcohol<\/strong><\/td>\n Molecular<\/strong>
\nformula<\/strong><\/td>\nNumber of carbon atoms per molecule<\/strong><\/td>\n Number of hydrogen atoms per molecule<\/strong><\/td>\n Relative molecular mass<\/strong><\/td>\n Heat of combustion (kJ mol-1<\/sup>)<\/strong><\/td>\n<\/tr>\n \n Methanol<\/td>\n CH3<\/sub>OH<\/td>\n 1<\/td>\n 4<\/td>\n 32<\/td>\n -728<\/td>\n<\/tr>\n \n Ethanol<\/td>\n C2<\/sub>H5<\/sub>OH<\/td>\n 2<\/td>\n 6<\/td>\n 46<\/td>\n -1376<\/td>\n<\/tr>\n \n Propan-1-ol<\/td>\n C3<\/sub>H7<\/sub>OH<\/td>\n 3<\/td>\n 8<\/td>\n 60<\/td>\n -2016<\/td>\n<\/tr>\n \n Butan-1-ol<\/td>\n C4<\/sub>H9<\/sub>OH<\/td>\n 4<\/td>\n 10<\/td>\n 74<\/td>\n -2678<\/td>\n<\/tr>\n \n Pentan-1-ol<\/td>\n C5<\/sub>H11<\/sub>OH<\/td>\n 5<\/td>\n 12<\/td>\n 88<\/td>\n -3332<\/td>\n<\/tr>\n \n Hexan-1-ol<\/td>\n C6<\/sub>H13<\/sub>OH<\/td>\n 6<\/td>\n 14<\/td>\n 102<\/td>\n -3981<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n \n
\n
\n[C] + O2<\/sub>(g) \u2192 CO2<\/sub>(g) + heat<\/li>\n
\n[H] + \u00bd O2<\/sub>(g) \u2192 H2<\/sub>O(g) + heat<\/li>\n\n\n
\n Pair of alcohols<\/strong><\/td>\n Difference in the heat of combustion (kJ)<\/strong><\/td>\n<\/tr>\n \n Methanol and ethanol<\/td>\n 1376 – 728 = 648<\/td>\n<\/tr>\n \n Ethanol and propan-1-ol<\/td>\n 2016 – 1376 = 640<\/td>\n<\/tr>\n \n Propan-1-ol and butan-1-ol<\/td>\n 2678 – 2016 = 662<\/td>\n<\/tr>\n \n Butan-1-ol and pentan-1-ol<\/td>\n 3332 – 2678 = 654<\/td>\n<\/tr>\n \n Pentan-1-ol and hexan-1-ol<\/td>\n 3981 – 3332 = 649<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n
\n(b) The constant increase in the heat of combustion of the successive members of alcohol is due to the extra heat given out by the extra one carbon atom and two hydrogen atoms in the -CH2<\/sub> group.<\/p>\n
\n<\/p>\nHeat of combustion of alcohols experiment<\/strong><\/h2>\n
\nProblem statement:<\/strong> Does an alcohol with a higher number of carbon atoms per molecule have a higher heat of combustion?
\nHypothesis:<\/strong> The higher the number of carbon atoms per alcohol molecule, the higher is the heat of combustion.
\nVariables:<\/strong>
\n(a) Manipulated variable : Different types of alcohols\/Number of carbon atoms per molecule of alcohol
\n(b) Responding variable : Heat of combustion
\n(c) Controlled variables : Volume of water, copper can, thermometer
\nMaterials:<\/strong> Methanol, ethanol, propan-1-ol, butan-1-ol, water.
\nApparatus:<\/strong> Copper can, tripod stand, thermometer (0 – 100\u00b0C), 100 cm3<\/sup> measuring cylinder, spirit lamps, electronic balance, pipe-clay triangle, windshield, wooden block.
\nProcedure:<\/strong><\/p>\n\n
\n<\/li>\n
\n
\n<\/strong><\/p>\n
\n1. Heat of combustion of methanol
\n<\/strong>
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\n2.<\/strong> Similarly, the heats of combustion of ethanol, propan-1 -ol and butan-1 -ol can be calculated.
\nDiscussion:<\/strong><\/p>\n\n
\n(a) The combustion of alcohol is not always complete. Instead of carbon dioxide and water being formed, carbon and carbon monoxide might be formed due to the incomplete combustion.
\n(b) Some heat is lost to the surroundings during combustion.
\n(c) A small quantity of the alcohol has been evaporated.<\/li>\n
\n(a) The flame from the burning of alcohol must always touch the base of the copper can.
\n(b) A thin copper can is used. Copper is a good conductor of heat, thus it can transfer the heat given out during the combustion of alcohol to the water.
\n(c) A wire gauze is not used in the experiment because it might absorb some of the heat given out during the combustion.
\n(d) When the flame has been put out, the spirit lamp must be weighed immediately because alcohols evaporate easily.
\n(e) The water in the copper can must be stirred throughout the whole experiment to ensure that the temperature of the water is uniform.
\n(f) A windshield is used to shield the flame from air currents. Air currents accelerate heat loss to the surroundings.<\/li>\n<\/ol>\n
\nThe heat of combustion increases as the number of carbon and hydrogen atoms per alcohol molecule increases. Thus, the hypothesis is accepted.<\/p>\nHow to calculate heat combustion example problems with solutions<\/strong><\/h2>\n
\n[Specific heat capacity of water: 4.2 J g-1<\/sup> \u00b0C-1<\/sup>; density of water: 1 g cm-3<\/sup>]
\nSolution:<\/strong><\/p>\n
\n<\/p>\n
\nVolume of water used = 200 cm3
\n<\/sup>Initial temperature of water = 29.0\u00b0C
\nHighest temperature of water = 59.0\u00b0C
\nMass of spirit lamp and ethanol before combustion = 245.85 g
\nMass of spirit lamp and ethanol after combustion = 244.95 g
\nBased on the results, calculate the heat of combustion of ethanol and construct the energy level diagram for the complete combustion of ethanol.
\n[Specific heat capacity of water: 4.2 J g-1<\/sup> \u00b0C-1<\/sup>; density of water: 1 g cm-3<\/sup>; relative atomic mass: H, 1; C, 12; O,16]
\nSolution:<\/strong>
\n
\n<\/p>\n","protected":false},"excerpt":{"rendered":"