Classification of Hydrocarbons

Classification of Hydrocarbons

The compounds containing only carbon and hydrogen in their molecules are called hydrocarbons.
Hydrocarbons are classified into two categories known as open chain hydrocarbons and closed chain hydrocarbons. Open chain hydrocarbons are also called aliphatic hydrocarbons or acyclic hydrocarbons.

Open and closed chain hydrocarbons
Let us observe the following structural formulae of different hydrocarbons.
1) CH3–CH2–CH2–CH2–CH3 n-pentane, a straight chain compound.

2) Classification of Hydrocarbons 1 Iso pentane, a branched chain compound

3) Classification of Hydrocarbons 2 cyclo pentane, a cyclic compound or a ring compound

In the first example you will notice that all carbons are linked to one another resulting a linear structure, where as in the second example four carbons are linked in linear way and the fifth carbon is linked to the parent chain resulting a branch. In the third example we find that carbon chain is closed to form a ring. So, it is a closed chain hydrocarbon or ring hydrocarbon.

All hydrocarbons (both Aliphatic and cyclic hydrocarbons) are again classified as Alkanes, Alkenes and Alkynes:
1) Hydrocarbons containing only single bonds between carbon atoms are called Alkanes.
2) Hydrocarbons containing atleast one double bond between carbon atoms are called Alkenes, and
3) Hydrocarbons containing atleast one triple between carbon atoms are called Alkynes.

Saturated and unsaturated hydrocarbons
The hydrocarbons containing only CC single bonds are known as saturated hydrocarbons. All alkanes are saturated hydrocarbons. The hydrocarbons that contain at least one double bond (C=C) or contain atleast one triple bond (C ≡ C) between the two carbon atoms are called unsaturated hydrocarbons. Alkenes and Alkynes are the examples for unsaturated hydrocarbons.
Straight chain, branched chain and closed chain hydro carbon compounds may be saturated or unsaturated. See the following examples.
Classification of Hydrocarbons 3

Classification of Hydrocarbons 4

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